|
|
AMERON |
M. S. D. S. |
|
|
AMERON |
M. S. D. S. |
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : AMERLOCK 400 CURE
IDENTIFICATION NUMBER: 400C00000
PRODUCT CLASS : HIGH-SOLIDS EPOXY
HEALTH : DANGER HMIS/NFPA : H3F3R0
Ameron International
Protective Coatings Group
201 North Berry St.
Brea, CA 92821
EMERGENCY:800-424-9300 (ChemTrec)
24 Hours Emergency Hotline
INFORMATION: William B. Dances, PHONE: 714-529-1951 PREPARE DATE: 02/08/01
PREVIOUS REVISION DATE: 01/08/01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 BARIUM SULFATE 13462-86-7 25.0 %
(Also CAS# 7727-43-7. Trace contaminants @ppm: arsenic**1,
cadmium**2, lead**#10, chromium6**2, silica**100)
02 MAGNESIUM SILICATE 14807-96-6 25.0 %
(Respirable quartz** <0.1%)
03 XYLENE 1330-20-7 12.50 %
(STEL 150ppm; Ceiling 300ppm; trace contaminant benzene**# @<10ppm,
toluene#<1%)
(HAPS, SARA, CERCLA)
04 POLYAMIDE RESIN 68410-23-1 15.0 %
(Also CAS#s 68910-91-8 & 68082-29-1. TETA @ 6%)
05 NONYL PHENOL 84852-15-3 10.0 %
06 POLYAMINE 9046-10-0 10.0 %
07 DIISODECYL PHTHALATE 68515-49-1 5.0 %
(Also CAS# 26761-40-0. Manufacturer's exposure limit 5mg/m3)
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
08 FURFURYL ALCOHOL 98-00-0 5.0 %
(STEL 15ppm, 60mg/m3.)
09 ETHYL BENZENE 100-41-4 3.00 %
(STEL 125ppm)
(HAPS, SARA, CERCLA)
10 CLAY 68911-87-5 5.0 %
(CRYSTALLINE SILICA** @ <1%)
11 AMINE CARBOXYLATE Mixture 5.0 %
(Trace contaminants @ ppm arsenic** 0.14; lead**#, cadmium**,
chromium VI** 0.03; nickel** 34.1; mercury# 0.001)
EXPOSURE LIMITS
----- ACGIH ---- ----- OSHA ----- VP TOXICITY
TLV-TWA TLV-TWA PEL-TWA PEL-TWA mmHg LD50 LC50
ITEM ppm Mg/M3 ppm Mg/M3 @68F g/kg ppm
---------------------------------------------------------------------------
01 dna 5.0 dna 5.0 N.A. dna dna
02 dna 2.00 dna 2.000 N.A. dna dna
03 100 434 100 435 6.6 3.900 6700.000
04 dna dna dna dna N.A. 8.000 dna
05 dna dna dna dna N.A. 2.100 dna
06 dna dna dna dna N.A. 2.980 dna
07 dna dna dna dna N.A. dna dna
08 10 40 10 40(S) N.A. dna dna
09 100 434 100 435 7.1 dna dna
10 dna 3.0 dna 5.0 N.A. dna dna
11 dna dna dna dna N.A. dna dna
REGULATORY: **CALIF.TITLE 26:22-12000 (PROP 65). WARNING: This product
contains a chemical known to the State of California to cause cancer.
#CALIF.TITLE 26:22-12000 (PROP 65). WARNING: This product contains a
chemical known to the State of California to cause birth defects or other
reproductive harm. All ingredients are on TSCA inventory or are exempt.
Toxic chemicals marked (SARA, CERCLA, HAPs) are subject to reporting
requirements of SARA (40CFR 355 and 372), CERCLA (40CFR 302), or
HAPs (40CFR 63).
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
(S)=Skin; LD50=Dermal.rabbit; LC50=Inhalation,rat; dna=data not available;
na=not applicable
SECTION 3 - HAZARDS IDENTIFICATION
EXPOSURE EFFECTS: Vapor or spray mist or spattered material can be
harmful. Irritating to eyes, skin, and if inhaled; to nose and throat.
Excessive or prolonged inhalation can cause headache, nausea or dizziness.
Repeated and prolonged occupational overexposure to solvents is associated
with permanent brain and nervous system damage. Intentional abuse, misuse
or other massive exposure to solvents may cause multiple organ damage
and/or death.
OVER-EXPOSURE (prolonged or repeated use): CAN AGGRAVATE OR ACCENTUATE ANY
OF THESE EFFECTS.
SKIN: Severe irritant. Severe burns. Sensitization or allergic reaction,
such as rash or hives. Can be absorbed through skin. Can cause defatting
and drying of skin.
INHALATION: Irritant. Lung injury. Respiratory sensitization and
allergic reaction such as asthma. Central nervous system damage. Chemical
pneumonia. Xylene or toluene may cause irregular heart beat. Excessive
exposure to barytes dust may product "baritosis."
EYES: Severe irritant. Corneal injury. Irreversible burns and damage.
DO NOT wear contact lenses when using this material.
INGESTION: Can be fatal if swallowed. Aspiration into lungs can damage
lungs and cause chemical pneumonia. Can cause burns.
TARGET ORGANS: Kidneys. Liver. Lungs. Heart. Skin. Eyes. Stomach.
Central nervous system. Fetal defects.
MEDICAL CONDITIONS AGGRAVATED: Kidneys. Liver. Skin. Eyes.
Respiratory. Lungs.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION EYE
CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID PROCEDURES: INHALATION: Remove to fresh air. Restore normal
breathing. Treat symptomatically. See physician. SKIN: Wash thoroughly with
soap and water. Remove contaminated clothing.Consult physician if
irritation persists. EYES: Flush immediately with plenty of water for at
least 15 minutes and get medical attention. INGESTION: Drink 1 or 2 glasses
SECTION 4 - FIRST AID MEASURES
of water to dilute. Never give anything by mouth to an unconscious person.
Do not induce vomiting. Consult physician or poison control center
IMMEDIATELY. Treat symptomatically.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 85 F (SETA) LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 7.0 %
FLAMMABILITY - OSHA: FLAMMABLE - CLASS IC
DOT: FLAMMABLE
EXTINGUISHING MEDIA: FOAM CO2 DRY CHEMICAL
LOWEST FLASHING SOLVENT: 100-41-4
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when
exposed to extreme heat and pressure buildup. May produce a floating fire
hazard. Isolate from electrical equipment, sparks, heat and open flame.
Vapors may spread long distances, cause flash fire or ignite explosively.
FIREFIGHTING PROCEDURES: Wear full protective equipment, self-contained
breathing apparatus. Water may be used to cool closed containers to prevent
pressure build-up or explosion when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL, LEAKS: Remove all sources of ignition. Avoid breathing vapors.
Ventilate area. Use absorbent, inert cleanup materials. (DO NOT use
sawdust.) Remove absorbent material with non-sparking tools. Place in
separate container. Keep out of sewers and waterways. If entry is
threatened or occurs, notify local authorities.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORAGE: Keep container closed, upright when not in use.
Store in cool, dry, well-ventilated area. Avoid prolonged storage
temperatures above 100F. Use caution when pouring. Avoid breathing sanding
dust. Do not weld or flame cut on empty container.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Implement administrative and engineering controls to reduce
exposure. Provide sufficient ventilation in volume and pattern to keep air
contaminant concentrations below the TLV limits. Remove welding or flame
cutting decomposition products; follow current,ANSI Z49.1,"Safety in
Welding and Cutting". Refer to 29 CFR parts 1910 and 1915, for coating
operations; part 1910.146, Confined Spaces.
RESPIRATORY PROTECTION: Wear NIOSH/MSHA certified respirator designed to
remove a combination of particulates (dust or spray mist) and vapor. When
brushing, rolling or spreading; select the appropriate respiratory
protection for the conditions. For specific conditions, refer to current
"NIOSH Pocket Guide to Chemical Hazards". In confined or restricted
ventilation areas use air-line respirators or hoods. Refer to 29 CFR, OSHA
parts 1910.134 and 1915 for coating operations;part 1910.146 Confined
Spaces;ANSI Z88.2,Practices for Respiratory Protection; 42 CFR, part 84
Particulate Respirators.
PROTECTIVE CLOTHING AND EQUIPMENT: Dependent upon application method, wear
resistant coveralls, gloves and shoe coverings to prevent skin contact.
Wear solvent resistant glasses with splash guards or face shield to protect
eyes from splash, spatter and/or spray mist.Consult 29 CFR 1910.132, 133,
136, 138; ANSI Z87.1, Z41. Use explosion and spark-proof equipment.
HYGIENIC PRACTICES: Wash thoroughly after handling and before eating,
smoking or using toilet. Launder contaminated clothing before use. Destroy
contaminated leather and absorbent shoes, which cannot be decontaminated,
to prevent reuse.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE : 212 - 277 F VAPOR DENSITY : Is heavier than air
ODOR : SOLVENT WEIGHT PER GAL : 11.6729
APPEARANCE : LIQUID EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : NO Acetate
MIXED VOC, G/L : 168 MIXED THINNED VOC, G/L : 209
THINNER : 65 @ 0.5 pints PHOTOCHEMICALLY REACTIVE: Yes
VOLATILE VOLUME % : 27.46
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heat, open flame, arc or sparks.
INCOMPATIBILITY: Strong oxidizers, acids and alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: (BY FIRE, BURNING OR WELDING); CO, CO2.
NOx. Hydrogen chloride fumes. Aldehydes. SOx. Toxic gases or fumes.
ammonia
SECTION 10 - STABILITY AND REACTIVITY
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
TOXICOLOGICAL PROPERTIES: See Section 2.
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No Information.
SECTION 13 - DISPOSAL CONSIDERATIONS
EPA Waste No.: D001
DISPOSAL METHOD: Place in separate, appropriate, closed container in
accordance with all applicable local, State, and Federal regulations. This
material has NOT been tested by Toxicity Characteristic Leaching Procedure
(TCLP).
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: Paint
DOT HAZARD CLASS: 3 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: 1263 IMO: NA PACKING GROUP : III
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SECTION 15 - REGULATORY INFORMATION
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
SECTION 16 - OTHER INFORMATION