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AMERON |
M. S. D. S. |
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AMERON |
M. S. D. S. |
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : AMERCOAT 68HS RESIN
IDENTIFICATION NUMBER: 68HSB00071
PRODUCT CLASS : ZINC-RICH EPOXY PRIMER
HEALTH : WARNING HMIS/NFPA : H2F3R0
Ameron International
Protective Coatings Group
201 North Berry St.
Brea, CA 92821
EMERGENCY:800-424-9300 (ChemTrec)
24 Hours Emergency Hotline
INFORMATION: William B. Dances, PHONE: 714-529-1951 PREPARE DATE: 02/08/01
PREVIOUS REVISION DATE: 01/09/01
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 SILICA (QUARTZ**)* 14808-60-7 25.0 %
Fed OSHA: N NTP: Y ACGIH: N IARC: 2A
* Cancer or cancer suspect agent.
02 EPOXY RESIN 25068-38-6 20.0 %
(Also CAS# 25085-99-8. Diglycidyl ether 2ppm, phenyl glycidyl
ether**6ppm)
03 EPOXY RESIN 25036-25-3 15.0 %
(Epch**# @ <1ppm, Bisphenol A @ <100ppm)
(SARA, CERCLA)
04 METHYL N-AMYL KETONE 110-43-0 12.00 %
05 METHYL ISOBUTYL KETONE 108-10-1 10.30 %
(STEL 75ppm, 307 mg/m3)
(HAPS, SARA, CERCLA)
06 XYLENE 1330-20-7 4.40 %
(STEL 150ppm; Ceiling 300ppm; trace contaminant benzene**# @<10ppm,
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
toluene#<1%)
(HAPS, SARA, CERCLA)
07 + IRON OXIDE (RED) 1332-37-2 5.0 %
(AS FE FUME)
08 HIGH FLASH NAPHTHA 64742-95-6 3.40 %
(Mfg TLV 50ppm; trace contaminant benzene**#<30ppm SARA)
(CERCLA)
09 EPOXY RESIN 68413-24-1 5.0 %
(Epichlorohydrin**# @ <25 PPM)
10 1,2,4-Trimethyl benzene 95-63-6 2.50 %
(SARA, CERCLA)
11 Tetraethyl orthosilicate 78-10-4 5.0 %
(Moisture will generate ethanol)
12 RHEOLOGY ADDITIVE 121888-68-4 5.0 %
(Crystalline silica** @ <1%. Also CAS# 71011-24-0)
13 EPOXY RESIN 25036-25-3 5.0 %
(Epichlorohydrin**# @ 1ppm max, benzene**# <0.01%)
14 ETHYL BENZENE 100-41-4 1.00 %
(STEL 125ppm)
(HAPS, SARA, CERCLA)
EXPOSURE LIMITS
----- ACGIH ---- ----- OSHA ----- VP TOXICITY
TLV-TWA TLV-TWA PEL-TWA PEL-TWA mmHg LD50 LC50
ITEM ppm Mg/M3 ppm Mg/M3 @68F g/kg ppm
---------------------------------------------------------------------------
01 dna 0.05 dna 0.1 N.A. dna dna
02 dna dna dna dna N.A. 20.000 dna
03 dna dna dna dna(S) 6.0 5.000 5000.000
04 50 233 50 235 2.1 12.000 4000.000
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
EXPOSURE LIMITS
----- ACGIH ---- ----- OSHA ----- VP TOXICITY
TLV-TWA TLV-TWA PEL-TWA PEL-TWA mmHg LD50 LC50
ITEM ppm Mg/M3 ppm Mg/M3 @68F g/kg ppm
---------------------------------------------------------------------------
05 50 205 50 205 16.0 10.000 4000.000
06 100 434 100 435 6.6 3.900 6700.000
07 dna 5.0 dna 5.0 N.A. dna dna
08 dna dna 100 dna 2.7 3.100 3670.000
09 2.0 10.0 5.0 19.0 N.A. 2.000 dna
10 25.0000 125.00 25.000 125.000 1.0 dna dna
11 dna 85.0 dna 85.0 N.A. 5.800 dna
12 dna 3.0 dna 10.0 N.A. dna dna
13 dna 5.0 dna 5.0 N.A. 3.000 dna
14 100 434 100 435 7.1 dna dna
REGULATORY: + Pigment content is dependent on color. **CALIF.TITLE
26:22-12000 (PROP 65). WARNING: This product contains a chemical known to
the State of California to cause cancer. #CALIF.TITLE 26:22-12000 (PROP
65). WARNING: This product contains a chemical known to the State of
California to cause birth defects or other reproductive harm. All
ingredients are on TSCA inventory or are exempt. Toxic chemicals marked
(SARA, CERCLA, HAPs) are subject to reporting requirements of SARA (40CFR
355 and 372), CERCLA (40CFR 302), or
HAPs (40CFR 63).
(S)=Skin; LD50=Dermal.rabbit; LC50=Inhalation,rat; dna=data not available;
na=not applicable
SECTION 3 - HAZARDS IDENTIFICATION
EXPOSURE EFFECTS: Vapor or spray mist or spattered material can be
harmful. Irritating to eyes, skin, and if inhaled; to nose and throat.
Excessive or prolonged inhalation can cause headache, nausea or dizziness.
Repeated and prolonged occupational overexposure to solvents is associated
with permanent brain and nervous system damage. Intentional abuse, misuse
or other massive exposure to solvents may cause multiple organ damage
and/or death.
OVER-EXPOSURE (prolonged or repeated use): CAN AGGRAVATE OR ACCENTUATE ANY
OF THESE EFFECTS.
SKIN: Irritant. Sensitization or allergic reaction, such as rash or
hives. Can be absorbed through skin. Can cause defatting and drying of
skin.
INHALATION: Irritant. Lung injury. Respiratory sensitization and
allergic reaction such as asthma. Central nervous system damage. Welding
fumes can cause welding fume fever. Repeated exposure to silica dust can
SECTION 3 - HAZARDS IDENTIFICATION
cause silicosis. Crystalline silica may cause cancer. Risk of cancer
depends on duration and level of exposure to dust from sanding surfaces or
spray mist. Chemical pneumonia. Xylene or toluene may cause irregular
heart beat. High vapor concentrations may cause drowsiness. Repeated
exposure to iron dust can cause siderosis.
EYES: Severe irritant. Corneal injury.
INGESTION: Can be fatal if swallowed. Aspiration into lungs can damage
lungs and cause chemical pneumonia. Liver damage.
TARGET ORGANS: Kidneys. Liver. Lungs. Heart. Skin. Eyes. Stomach.
Central nervous system. Fetal defects.
MEDICAL CONDITIONS AGGRAVATED: Kidneys. Liver. Blood disorders. Skin.
Eyes. Respiratory. Allergies. Lungs.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION EYE
CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID PROCEDURES: INHALATION: Remove to fresh air. Restore normal
breathing. Treat symptomatically. See physician. SKIN: Wash thoroughly with
soap and water. Remove contaminated clothing.Consult physician if
irritation persists. EYES: Flush immediately with plenty of water for at
least 15 minutes and get medical attention. INGESTION: Drink 1 or 2 glasses
of water to dilute. Never give anything by mouth to an unconscious person.
Do not induce vomiting. Consult physician or poison control center
IMMEDIATELY. Treat symptomatically.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 82 F (SETA) LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 23.0 %
FLAMMABILITY - OSHA: FLAMMABLE - CLASS IC
DOT: FLAMMABLE
EXTINGUISHING MEDIA: FOAM CO2 DRY CHEMICAL
LOWEST FLASHING SOLVENT: 100-41-4
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when
exposed to extreme heat and pressure buildup. May produce a floating fire
hazard. Isolate from electrical equipment, sparks, heat and open flame.
Vapors may spread long distances, cause flash fire or ignite explosively.
SECTION 5 - FIRE FIGHTING MEASURES
FIREFIGHTING PROCEDURES: Wear full protective equipment, self-contained
breathing apparatus. Water may be used to cool closed containers to prevent
pressure build-up or explosion when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL, LEAKS: Remove all sources of ignition. Avoid breathing vapors.
Ventilate area. Use absorbent, inert cleanup materials. (DO NOT use
sawdust.) Remove absorbent material with non-sparking tools. Place in
separate container. Keep out of sewers and waterways. If entry is
threatened or occurs, notify local authorities.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORAGE: Keep container closed, upright when not in use.
Store in cool, dry, well-ventilated area. Avoid prolonged storage
temperatures above 100F. Use caution when pouring. Avoid breathing sanding
dust. Do not weld or flame cut on empty container.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Implement administrative and engineering controls to reduce
exposure. Provide sufficient ventilation in volume and pattern to keep air
contaminant concentrations below the TLV limits. Remove welding or flame
cutting decomposition products; follow current,ANSI Z49.1,"Safety in
Welding and Cutting". Refer to 29 CFR parts 1910 and 1915, for coating
operations; part 1910.146, Confined Spaces.
RESPIRATORY PROTECTION: Wear NIOSH/MSHA certified respirator designed to
remove a combination of particulates (dust or spray mist) and vapor. When
brushing, rolling or spreading; select the appropriate respiratory
protection for the conditions. For specific conditions, refer to current
"NIOSH Pocket Guide to Chemical Hazards". In confined or restricted
ventilation areas use air-line respirators or hoods. Refer to 29 CFR, OSHA
parts 1910.134 and 1915 for coating operations;part 1910.146 Confined
Spaces;ANSI Z88.2,Practices for Respiratory Protection; 42 CFR, part 84
Particulate Respirators.
PROTECTIVE CLOTHING AND EQUIPMENT: Dependent upon application method, wear
resistant coveralls, gloves and shoe coverings to prevent skin contact.
Wear solvent resistant glasses with splash guards or face shield to protect
eyes from splash, spatter and/or spray mist.Consult 29 CFR 1910.132, 133,
136, 138; ANSI Z87.1, Z41. Use explosion and spark-proof equipment.
HYGIENIC PRACTICES: Wash thoroughly after handling and before eating,
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
smoking or using toilet. Launder contaminated clothing before use. Destroy
contaminated leather and absorbent shoes, which cannot be decontaminated,
to prevent reuse.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE : 242 - 336 F VAPOR DENSITY : Is heavier than air
ODOR : SOLVENT WEIGHT PER GAL : 9.8590
APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : NO Acetate
MIXED VOC, G/L : 288 MIXED THINNED VOC, G/L : 336
THINNER : 65 @ 0.50PINTS PHOTOCHEMICALLY REACTIVE: Yes
VOLATILE VOLUME % : 51.73
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heat, open flame, arc or sparks. Water or moisture.
INCOMPATIBILITY: Strong oxidizers, acids and alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: (BY FIRE, BURNING OR WELDING); CO, CO2.
NOx. Hydrogen chloride fumes. Iron oxide fumes. Aldehydes. Phenols.
Silicon oxide fumes. Toxic gases or fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
TOXICOLOGICAL PROPERTIES: See Section 2. Crystalline silica (respirable
size, 10 microns or less). IARC Monograph on the Evaluation of Carcinogenic
Risk of Chemicals to Humans (Vol 68.1997) concludes that there is
sufficient evidence of carcinogenicity to experimental animals and limited
evidence of carcinogenicity to humans. - IARC Class 1.
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No Information.
SECTION 13 - DISPOSAL CONSIDERATIONS
EPA Waste No.: D001
DISPOSAL METHOD: Place in separate, appropriate, closed container in
accordance with all applicable local, State, and Federal regulations. This
material has NOT been tested by Toxicity Characteristic Leaching Procedure
(TCLP).
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: Paint
DOT HAZARD CLASS: 3 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: 1263 IMO: NA PACKING GROUP : III
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
SECTION 16 - OTHER INFORMATION