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AMERON |
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : AMERSHIELD WHITE RESIN
IDENTIFICATION NUMBER: AMSHB30000
PRODUCT CLASS : ALIPHATIC POLYURETHANE
HEALTH : WARNING HMIS/NFPA : H2F2R0
Ameron International
Protective Coatings Group
201 North Berry St.
Brea, CA 92821
EMERGENCY:800-424-9300 (ChemTrec)
24 Hours Emergency Hotline
INFORMATION: William B. Dances, PHONE: 714-529-1951 PREPARE DATE: 02/19/01
PREVIOUS REVISION DATE: 11/30/00
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
01 ACRYLIC RESIN POLYMER Mixture 30.0 %
(ETHYLHEXYL ACRYLATE @ <0.3%, MFG TLV 5PPM)
02 + TITANIUM DIOXIDE 13463-67-7 25.0 %
(As TiO2, trace impurities, <6% aluminum hydroxide, <10% amorphous
silica)
03 BUTYL ACETATE 123-86-4 14.20 %
(STEL 200ppm, 950mg/m3.)
(CERCLA)
04 POLYESTER RESIN dna 10.0 %
05 CALCIUM SILICATE 13983-17-0 10.0 %
06 OXOHEXYL ACETATE 88230-35-7 6.60 %
(Mfg TLV 50ppm)
07 SILICA (QUARTZ**)* 14808-60-7 10.0 %
Fed OSHA: N NTP: Y ACGIH: N IARC: 2A
* Cancer or cancer suspect agent. (Trace contaminants ppm: Ba 15;
Pb**#1; Cd**0.5; As**, Sb**, Ag<0.2; Se, Hg# <0.1)
08 SILICA (AMORPHOUS) 112926-00-8 5.0 %
(CAS # also 7631-86-9)
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
WT/WT %
ITEM -------------- CHEMICAL NAME --------------- CAS NUMBER LESS THAN
---------------------------------------------------------------------------
09 ETHYL ETHOXYPROPIONATE 763-69-9 1.40 %
(Mfg 50 ppm TWA, 100 ppm STEL; <0.01% butylated hydroxytoluene)
EXPOSURE LIMITS
----- ACGIH ---- ----- OSHA ----- VP TOXICITY
TLV-TWA TLV-TWA PEL-TWA PEL-TWA mmHg LD50 LC50
ITEM ppm Mg/M3 ppm Mg/M3 @68F g/kg ppm
---------------------------------------------------------------------------
01 dna dna dna dna N.A. dna dna
02 dna 5.00 dna 5.000 N.A. 10.000 6820.000
03 150.0000 713.00 150.000 710.000 10.0 10.000 1800.000
04 dna dna dna dna N.A. dna dna
05 dna 5.00 dna 5.000 N.A. dna dna
06 dna dna dna dna 1.4 dna dna
07 dna 0.05 dna 0.1 N.A. dna dna
08 dna 3.0 dna 5.0 N.A. dna dna
09 dna dna dna dna 1.5 20.000 1000.000
REGULATORY: + Pigment content is dependent on color. **CALIF.TITLE
26:22-12000 (PROP 65). WARNING: This product contains a chemical known to
the State of California to cause cancer. #CALIF.TITLE 26:22-12000 (PROP
65). WARNING: This product contains a chemical known to the State of
California to cause birth defects or other reproductive harm. All
ingredients are on TSCA inventory or are exempt. Toxic chemicals marked
(SARA, CERCLA, HAPs) are subject to reporting requirements of SARA (40CFR
355 and 372), CERCLA (40CFR 302), or
HAPs (40CFR 63).
(S)=Skin; LD50=Dermal.rabbit; LC50=Inhalation,rat; dna=data not available;
na=not applicable
SECTION 3 - HAZARDS IDENTIFICATION
EXPOSURE EFFECTS: Vapor or spray mist or spattered material can be
harmful. Irritating to eyes, skin, and if inhaled; to nose and throat.
Excessive or prolonged inhalation can cause headache, nausea or dizziness.
Repeated and prolonged occupational overexposure to solvents is associated
with permanent brain and nervous system damage. Intentional abuse, misuse
or other massive exposure to solvents may cause multiple organ damage
and/or death.
OVER-EXPOSURE (prolonged or repeated use): CAN AGGRAVATE OR ACCENTUATE ANY
OF THESE EFFECTS.
SECTION 3 - HAZARDS IDENTIFICATION
SKIN: Irritant. Can cause defatting and drying of skin.
INHALATION: Irritant. Lung injury. Central nervous system damage.
Repeated exposure to silica dust can cause silicosis. Crystalline silica
may cause cancer. Risk of cancer depends on duration and level of exposure
to dust from sanding surfaces or spray mist. Chemical pneumonia. High
vapor concentrations may cause drowsiness.
EYES: Severe irritant. DO NOT wear contact lenses when using this
material.
INGESTION: Harmful if swallowed. Aspiration into lungs can damage lungs
and cause chemical pneumonia.
TARGET ORGANS: Kidneys. Liver. Lungs. Skin. Eyes. Stomach. Spleen.
Central nervous system.
MEDICAL CONDITIONS AGGRAVATED: Skin. Respiratory.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION INGESTION EYE
CONTACT
SECTION 4 - FIRST AID MEASURES
FIRST AID PROCEDURES: INHALATION: Remove to fresh air. Restore normal
breathing. Treat symptomatically. See physician. SKIN: Wash thoroughly with
soap and water. Remove contaminated clothing.Consult physician if
irritation persists. EYES: Flush immediately with plenty of water for at
least 15 minutes and get medical attention. INGESTION: Drink 1 or 2 glasses
of water to dilute. Never give anything by mouth to an unconscious person.
Do not induce vomiting. Consult physician or poison control center
IMMEDIATELY. Treat symptomatically.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 110 F (SETA) LOWER EXPLOSIVE LIMIT: 1.0 %
UPPER EXPLOSIVE LIMIT: 8.0 %
FLAMMABILITY - OSHA: COMBUSTIBLE - CLASS II
DOT: FLAMMABLE
EXTINGUISHING MEDIA: FOAM CO2 DRY CHEMICAL
LOWEST FLASHING SOLVENT: 123-86-4
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when
exposed to extreme heat and pressure buildup. May produce a floating fire
SECTION 5 - FIRE FIGHTING MEASURES
hazard. Isolate from electrical equipment, sparks, heat and open flame.
Vapors may spread long distances, cause flash fire or ignite explosively.
FIREFIGHTING PROCEDURES: Wear full protective equipment, self-contained
breathing apparatus. Water may be used to cool closed containers to prevent
pressure build-up or explosion when exposed to extreme heat.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SPILL, LEAKS: Remove all sources of ignition. Avoid breathing vapors.
Ventilate area. Use absorbent, inert cleanup materials. (DO NOT use
sawdust.) Remove absorbent material with non-sparking tools. Place in
separate container. Keep out of sewers and waterways. If entry is
threatened or occurs, notify local authorities.
SECTION 7 - HANDLING AND STORAGE
HANDLING AND STORAGE: Keep container closed, upright when not in use.
Store in cool, dry, well-ventilated area. Avoid prolonged storage
temperatures above 100F. Use caution when pouring. Avoid breathing sanding
dust. Do not weld or flame cut on empty container.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Implement administrative and engineering controls to reduce
exposure. Provide sufficient ventilation in volume and pattern to keep air
contaminant concentrations below the TLV limits. Remove welding or flame
cutting decomposition products; follow current,ANSI Z49.1,"Safety in
Welding and Cutting". Refer to 29 CFR parts 1910 and 1915, for coating
operations; part 1910.146, Confined Spaces.
RESPIRATORY PROTECTION: Wear NIOSH/MSHA certified respirator designed to
remove a combination of particulates (dust or spray mist) and vapor. When
brushing, rolling or spreading; select the appropriate respiratory
protection for the conditions. For specific conditions, refer to current
"NIOSH Pocket Guide to Chemical Hazards". In confined or restricted
ventilation areas use air-line respirators or hoods. Refer to 29 CFR, OSHA
parts 1910.134 and 1915 for coating operations;part 1910.146 Confined
Spaces;ANSI Z88.2,Practices for Respiratory Protection; 42 CFR, part 84
Particulate Respirators.
PROTECTIVE CLOTHING AND EQUIPMENT: Dependent upon application method, wear
resistant coveralls, gloves and shoe coverings to prevent skin contact.
Wear solvent resistant glasses with splash guards or face shield to protect
eyes from splash, spatter and/or spray mist.Consult 29 CFR 1910.132, 133,
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
136, 138; ANSI Z87.1, Z41. Use explosion and spark-proof equipment.
HYGIENIC PRACTICES: Wash thoroughly after handling and before eating,
smoking or using toilet. Launder contaminated clothing before use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
BOILING RANGE : 252 - 329 F VAPOR DENSITY : Is heavier than air
ODOR : SOLVENT WEIGHT PER GAL : 11.4598
APPEARANCE : LIQUID EVAPORATION RATE: Is faster than Butyl
SOLUBILITY IN H2O : NO Acetate
MIXED VOC, G/L : 264 MIXED THINNED VOC, G/L : 323
THINNER : 65 @ 1.00PINTS PHOTOCHEMICALLY REACTIVE: No
VOLATILE VOLUME % : 100.00
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heat, open flame, arc or sparks.
INCOMPATIBILITY: Strong oxidizers, acids and alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: (BY FIRE, BURNING OR WELDING); CO, CO2.
Toxic gases or fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
SECTION 11 - TOXICOLOGICAL PROPERTIES
TOXICOLOGICAL PROPERTIES: See Section 2. Crystalline silica (respirable
size, 10 microns or less). IARC Monograph on the Evaluation of Carcinogenic
Risk of Chemicals to Humans (Vol 68.1997) concludes that there is
sufficient evidence of carcinogenicity to experimental animals and limited
evidence of carcinogenicity to humans. - IARC Class 1.
SECTION 12 - ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: No Information.
SECTION 13 - DISPOSAL CONSIDERATIONS
EPA Waste No.: D001
DISPOSAL METHOD: Place in separate, appropriate, closed container in
accordance with all applicable local, State, and Federal regulations. This
material has NOT been tested by Toxicity Characteristic Leaching Procedure
(TCLP).
SECTION 14 - TRANSPORTATION INFORMATION
DOT PROPER SHIPPING NAME: Paint
DOT HAZARD CLASS: 3 HAZARD SUBCLASS: NA
DOT UN/NA NUMBER: 1263 IMO: NA PACKING GROUP : III
SECTION 15 - REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous materials are among the top five ingredients.
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
No non-hazardous ingredients are present at greater than 3%.
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
SECTION 16 - OTHER INFORMATION